The sound of gunfire has echoed through Ukraine's capital Kyiv as Russian tanks were filmed entering the city for the first time.
Ukraine's Ministry of Defence called on those living in the northern outskirts, where the tanks were seen, to make fire bombs "to neutralise the enemy".
The European Union has announced new sanctions to freeze Vladimir Putin's personal assets in Europe.
The Kremlin, meanwhile, says that Russia is ready for talks with Ukraine.
Spokesman Dmitry Peskov said talks would have to be about Ukraine declaring a "neutral status" - which would include "demilitarisation".
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